Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy
This article was published in the Journal of Analytical Atomic Spectrometry [© 2014 Royal Society of Chemistry] and the definite version is available at : 10.1039/c3ja50199j
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© 2014 Royal Society of Chemistry
2017
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10361-80072017-04-17T04:52:53Z Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy Haider, A F M Yusuf Ira, Mehera Kamal Khan, Z. H. Abedin, K. M. Department of Mathematics and Natural Sciences, BRAC University Atom lasers Atomic emission spectroscopy Atoms Nitrogen This article was published in the Journal of Analytical Atomic Spectrometry [© 2014 Royal Society of Chemistry] and the definite version is available at : 10.1039/c3ja50199j Lifetimes of the excited 2P2 (3P) 3p 4S3/2 level of a nitrogen atom corresponding to transitions to different lower states have been estimated by measuring the line intensity of a transition as a function of the delay time between the Q-switching of the laser and the gating of the window of the ICCD. This novel time resolved laser-induced breakdown spectroscopic technique is explained in the paper. The lifetimes of the upper level 2P2 (3P) 3p 4S3/2 corresponding to the three transitions to 2P 2 (3P) 3s 4P1/2 (742.346 nm), 2P2 (3P) 3s 4P3/2 (744.27 nm) and 2P2 (3P) 3s 4P5/2 (746.851 nm) were measured by this technique. The corresponding average lifetimes (τ) of these transitions were 199 ns, 105 ns and 68 ns. These values compare pretty well with the calculated lifetimes of 203.8 ns, 96.7 ns and 59.2 ns for the above three transitions as reported by Hibbert et al. The plasma temperature (atomic excitation temperature) decay time was found to be 1133 ns. This novel technique of estimating the lifetime of an excited state of an atom/ion is yet another very useful application of LIBS as a versatile analytical tool. Published 2017-04-09T09:14:52Z 2017-04-09T09:14:52Z 2014-08 Article Haider, A. F. M. Y., Ira, M. K., Khan, Z. H., & Abedin, K. M. (2014). Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy. Journal of Analytical Atomic Spectrometry, 29(8), 1385-1392. doi:10.1039/c3ja50199j 02679477 http://hdl.handle.net/10361/8007 en http://pubs.rsc.org/en/content/articlelanding/2014/ja/c3ja50199j#!divAbstract © 2014 Royal Society of Chemistry |
| institution |
Brac University |
| collection |
Institutional Repository |
| language |
English |
| topic |
Atom lasers Atomic emission spectroscopy Atoms Nitrogen |
| spellingShingle |
Atom lasers Atomic emission spectroscopy Atoms Nitrogen Haider, A F M Yusuf Ira, Mehera Kamal Khan, Z. H. Abedin, K. M. Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| description |
This article was published in the Journal of Analytical Atomic Spectrometry [© 2014 Royal Society of Chemistry] and the definite version is available at : 10.1039/c3ja50199j |
| author2 |
Department of Mathematics and Natural Sciences, BRAC University |
| author_facet |
Department of Mathematics and Natural Sciences, BRAC University Haider, A F M Yusuf Ira, Mehera Kamal Khan, Z. H. Abedin, K. M. |
| format |
Article |
| author |
Haider, A F M Yusuf Ira, Mehera Kamal Khan, Z. H. Abedin, K. M. |
| author_sort |
Haider, A F M Yusuf |
| title |
Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| title_short |
Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| title_full |
Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| title_fullStr |
Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| title_full_unstemmed |
Radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| title_sort |
radiative lifetime measurement of excited neutral nitrogen atoms by time resolved laser-induced breakdown spectroscopy |
| publisher |
© 2014 Royal Society of Chemistry |
| publishDate |
2017 |
| url |
http://hdl.handle.net/10361/8007 |
| work_keys_str_mv |
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